Highly Efficient Heterogeneous Pd@POPs Catalyst for the N-Formylation of Amine and CO2

Utilization of CO2 for the production fine chemicals has become a research hotspot long time. In order to make use CO2, we developed highly efficient heterogeneous catalyst (denoted as Pd@POPs) N-formylation reaction amine and under mild conditions. The Pd was based on porous organic polymer derived from solvothermal polymerization vinyl-functionalized PPh3. A series characterizations comparative experiments demonstrated that Pd@POPs high BET (Brunauer-Emmett-Teller) surface areas, hierarchical pore structure, uniform dispersion active sites resulting formation strong coordination bonds between species P atoms in (POP) support. addition excellent activity, shows good stability CO2.